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X-Ray analysis of benzylideneaniline and of two para-substituted derivatives has shown that the aniline ring is twisted out of the C–N![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
C–C plane by 40–55°, a result that bears on the apparently anomalous u.v. spectrum of benzylideneaniline derivatives.
H. B. Bürgi and J. D. Dunitz, J. Chem. Soc. D, 1969, 472 DOI: 10.1039/C29690000472
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