The rearrangement of some steroidal hydroxy-cyclohexenones under a variety of acidic conditions has been studied. 2α-Hydroxy-cholest-4-en-3-ones give, in general, products with functionality at C-6 while C-2 becomes saturated. Enol acetates are also formed, but only one case of aromatisation was observed.
K. M. Baker and B. R. Davis, J. Chem. Soc. C, 1968, 2743 DOI: 10.1039/J39680002743
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