The dienone–phenol rearrangements of the two stereoisomers (IIa) and (IIb) of 2,3,7,8,9,9a-hexahydro-6-hydroxy-5-methoxy-1-methyl-1H-benzo[de]quinoline-7-spiro-3′-methoxycyclohexa-2′,5′-dien-4′-one and the dienol–benzene rearrangement of the corresponding dienol (VIII) are described. The configurations of (IIa) and (IIb) have been assigned by chemical and spectroscopic methods.
T. Kametani, F. Satoh, H. Yagi and K. Fukumoto, J. Chem. Soc. C, 1968, 1003 DOI: 10.1039/J39680001003
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