Issue 0, 1968
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Chemistry of the metal carbonyls. Part XLIV. Reactions of pentacarbonylrhenate(I) and dicarbonyl(π-cyclopentadienyl)ferrate(II) with 3,3,3-trifluoropropyne and pentafluorophenylacetylene

M. I. Bruce,   D. A. Harbourne,   F. Waugh  and  F. G. A. Stone  

Abstract

The anions [Re(CO)5]– and [π-C5H5Fe(CO)2]– react with 3,3,3-trifluoropropyne to give the trifluoropropenyl complexes cis-CF3·CH:CH[Re(CO)5] and cis-CF3·CH:CH[Fe(CO)2π-C5H5], respectively. The product of the reaction between pentafluorophenylacetylene and [Re(CO)5]– is p-HC⋮C·C6F4Re(CO)5, but under similar conditions [π-C5H5Fe(CO)2]– affords cis-p-HC6F4·CH:CH[Fe(CO)2π-C5H5]. The n.m.r., i.r., and mass spectra of the new compounds are discussed.

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Article information

DOI
https://doi.org/10.1039/J19680000895
Article type
Paper

J. Chem. Soc. A, 1968, 895-898

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Chemistry of the metal carbonyls. Part XLIV. Reactions of pentacarbonylrhenate(I) and dicarbonyl(π-cyclopentadienyl)ferrate(II) with 3,3,3-trifluoropropyne and pentafluorophenylacetylene

M. I. Bruce, D. A. Harbourne, F. Waugh and F. G. A. Stone, J. Chem. Soc. A, 1968, 895 DOI: 10.1039/J19680000895

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