Issue 0, 1968
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Chemistry of the metal carbonyls. Part XLIII. Perfluoroallenyl-rhenium and -iron complexes

R. J. Goodfellow,   M. Green,   N. Mayne,   A. J. Rest  and  F. G. A. Stone  

Abstract

Treatment of hexafluorobut-2-yne with the anion [π-C5H5Fe(CO)2]– affords the perfluoroallenyl complex σ-CF2:C:C(CF3) Fe(CO)2(π-C5H5). The corresponding perfluoroallenylrhenium complex is formed in the reaction between [Re(CO)5]– and hexafluorobut-2-yne, but in addition a binuclear rhenium complex of formula C8F11H[Re(CO)5]2 is produced. The structures of the complexes have been established by infrared, 19F and 1H n.m.r. spectroscopy, including 19F–19F decoupling studies on the binuclear rhenium compound.

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Article information

DOI
https://doi.org/10.1039/J19680000177
Article type
Paper

J. Chem. Soc. A, 1968, 177-180

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Chemistry of the metal carbonyls. Part XLIII. Perfluoroallenyl-rhenium and -iron complexes

R. J. Goodfellow, M. Green, N. Mayne, A. J. Rest and F. G. A. Stone, J. Chem. Soc. A, 1968, 177 DOI: 10.1039/J19680000177

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