A simple relation has been developed for estimating the s-character of the atomic orbitals forming a bond in terms of the electronegativity, ionic character, double-bond character and p electron defect. The s-character of the bonding orbitals in a large number of compounds has been calculated using this relation.
S. Chandra, Trans. Faraday Soc., 1967, 63, 1569 DOI: 10.1039/TF9676301569
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