The molar heats of sublimation of the compounds Ph3M (M = B, Al, Ga, and In) have been determined by a gravimetric effusion technique. The values are 26·6 ± 0·3, 34·8 ± 0·6, 32·9 ± 0·9, and 33·6 ± 0·4 kcal. mole–1, respectively. Possible reasons for these high values are discussed.
N. N. Greenwood, P. G. Perkins and M. E. Twentyman, J. Chem. Soc. A, 1967, 2109 DOI: 10.1039/J19670002109
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