The red precipitate formed when potassium pertechnetate is reduced with iodide ions is the pentachlorohydroxy-complex K2Tc(OH)Cl5. The compound has a cubic crystal structure and is isomorphous with K2TcCl6. It is paramagnetic and has an electronic spectrum analogous to that of the hexachloro-salt.
M. Elder, J. E. Fergusson, G. J. Gainsford, J. H. Hickford and B. R. Penfold, J. Chem. Soc. A, 1967, 1423 DOI: 10.1039/J19670001423
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