Volume 62, 1966
From the journal:

Transactions of the Faraday Society

Photolysis of dimethyl carbonate

M. J. Yee Quee  and  J. C. J. Thynne  

Abstract

The gas-phase photolysis of dimethyl carbonate (DMC) has been studied in the temperature range 41–93°C. Methoxyl and methyl radicals are generated in this photolysis and their reactions have been studied. Arrhenius parameters have been measured for the following reactions: [graphic omitted]

A value of 1014.13(mole–1 cm3 sec–1) at 41°C has been obtained for the auto-disproportionation of methoxyl radicals: 2CH3O→CH3OH+CH2O

Using this velocity constant a value of ca. 67 has been deduced for the disproportionation ratio of methoxyl radicals, Δ(CH3O, CH3O).

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Article information

DOI
https://doi.org/10.1039/TF9666203154
Article type
Paper

Trans. Faraday Soc., 1966,62, 3154-3161

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Photolysis of dimethyl carbonate

M. J. Y. Quee and J. C. J. Thynne, Trans. Faraday Soc., 1966, 62, 3154 DOI: 10.1039/TF9666203154

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