The determination by cryoscopy of precise values of the osmotic coefficients of ammonium chloride and bromide in water at 0°C shows that earlier reports of abnormal behaviour in dilute solution should be discounted. The osmotic coefficients of the ammonium salts are very similar to those of the corresponding potassium salts. Specific interaction coefficients are reported.
R. Garnsey and J. E. Prue, Trans. Faraday Soc., 1966, 62, 1265 DOI: 10.1039/TF9666201265
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