(–)- and (+)-Perhydro-3,8-dimethylazulen-5-one have been brominated; the former gave two monobromoketones and the latter one monobromo-ketone. The stereochemistry of these α-bromo-ketones is discussed in the light of infrared and ultraviolet spectra and optical rotatory dispersion studies.
K. Takeda, H. Minato, T. Terasawa, M. Ishikawa and C. Yanaihara, J. Chem. Soc. C, 1966, 2095 DOI: 10.1039/J39660002095
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