Methyl vinyl ketone and 2-mercaptoethylamine react under basic conditions to yield a 1,4-thiazepine. Cyclisation of products from reaction of thioglycollic acid with 1,2-epoxides yield substituted 1,4-thioxans.
D. K. Black, J. Chem. Soc. C, 1966, 1708 DOI: 10.1039/J39660001708
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