The preparation of the six racemic forms of menthane is described and their n.m.r. spectra discussed. Specific chemical routes to (–)-cis- and (+)-trans-carane are described; the properties of these isomers can be explained by their stereochemistry.
W. Cocker, P. V. R. Shannon and P. A. Staniland, J. Chem. Soc. C, 1966, 946 DOI: 10.1039/J39660000946
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