The e.s.r. spectra of arylsulphonyl free radicals show only small hyperfine splittings, the coupling with aromatic ortho hydrogens being greater than with a para hydrogen. This shows that these radicals have a significant degree of σ-character.
M. McMillan and W. A. Waters, J. Chem. Soc. B, 1966, 422 DOI: 10.1039/J29660000422
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