In the crystal structure of bis(ethyl acetoacetato)copper(II) the copper makes an axial approach of 3·12 Å to the –CH= group of a neighbouring molecule. This carbon atom is not coplanar with the remaining atoms of the molecule, but is displaced towards the approaching copper.
D. Hall, A. J. McKinnon and T. N. Waters, J. Chem. Soc. A, 1966, 615 DOI: 10.1039/J19660000615
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