Issue 0, 1966

The reactivity of co-ordinated carbonate. Part I. Exchange of oxygen atoms between carbonatotetra-amminecobalt(III) and [18O]water

Abstract

The exchange of oxygen atoms between carbonatotetra-amminecobalt(III) cation and solvent water has been studied, using the oxygen-18 isotope. All three oxygen atoms of the co-ordinated carbonate group appear to exchange at the same rate, and this is interpreted in terms of a reversible one-ended dissociation reaction.

Article information

Article type
Paper

J. Chem. Soc. A, 1966, 184-186

The reactivity of co-ordinated carbonate. Part I. Exchange of oxygen atoms between carbonatotetra-amminecobalt(III) and [18O]water

D. McKenzie, C. O'Connor and A. L. Odell, J. Chem. Soc. A, 1966, 184 DOI: 10.1039/J19660000184

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