Issue 12, 2002
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Reaction of α-carbanion of imines with N-tosylimines: a facile route to β-aminoaldehydes and 1,3-diamines

Xue-Long Hou,*a   Yu-Mei Luo,a   Ke Yuana  and  Li-Xin Daia  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 FengLin Lu, Shanghai 200032, China
E-mail: xlhou@pub.sioc.ac.cn

Abstract

Deprotonation of aldimines by LDA, followed by trapping of the resulting carbanion with N-tosylimines and hydrolysis or reduction provides a convenient access to β-aminoaldehydes or 1,3-diamines.

Graphical abstract: Reaction of α-carbanion of imines with N-tosylimines: a facile route to β-aminoaldehydes and 1,3-diamines

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Article information

DOI
https://doi.org/10.1039/B200198E
Article type
Paper
Submitted
08 Jan 2002
Accepted
24 Apr 2002
First published
17 May 2002

J. Chem. Soc., Perkin Trans. 1, 2002, 1487-1490

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Reaction of α-carbanion of imines with N-tosylimines: a facile route to β-aminoaldehydes and 1,3-diamines

X. Hou, Y. Luo, K. Yuan and L. Dai, J. Chem. Soc., Perkin Trans. 1, 2002, 1487 DOI: 10.1039/B200198E

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