Issue 2, 1986
From the journal:

Journal of the Chemical Society, Dalton Transactions

Structure of 2,4-dinitrobenzenesulphenylimino(triphenyl)phosphorane, Ph3PNSC6H3(NO2)2-2,4

Kwok W. Chiu,   John Fawcett,   Raymond D. W. Kemmitt  and  David R. Russell  

Abstract

The compound Ph3PNSC6H3(NO2)2-2,4 was isolated from the reaction of the 2,4–dinitrobenzenesulphenamide of 1,4-dihydro- 1,4- iminonaphthalene with trans-[IrCl(CO)(PPh3)2], and its structure has been determined. Bond angles at N [123.1(5)°] and S [101.4(5)°] and the bond distances P[double bond, length half m-dash]N [1.566(7)Å], S–N [1.660(8)Å], and C–S [1.728(11)Å] indicate the presence of localised double and single bonds with no significant declocalisation of the lone-pair charge at nitrogen. The 2,4-dinitrophenyl ring is –8.9° out of the N,S,C plane and the PNSC torsion angle is –134.6°.

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Article information

DOI
https://doi.org/10.1039/DT9860000457
Article type
Paper

J. Chem. Soc., Dalton Trans., 1986, 457-458

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Structure of 2,4-dinitrobenzenesulphenylimino(triphenyl)phosphorane, Ph3PNSC6H3(NO2)2-2,4

K. W. Chiu, J. Fawcett, R. D. W. Kemmitt and D. R. Russell, J. Chem. Soc., Dalton Trans., 1986, 457 DOI: 10.1039/DT9860000457

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