A new type of metalloalkyl ylide has been produced which can be used to convert a ketone or aldehyde function directly to a very nucleophilic double bond; this affords a method for preparing quaternary carbons either by ring closure or external electrophilic reaction.
S. J. Hannon and T. G. Traylor, J. Chem. Soc., Chem. Commun., 1975, 630 DOI: 10.1039/C39750000630
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