Volume 64, 1968

Equilibrium vapour pressures of carbon monoxide + nitrogen solid solutions

Abstract

Vapour pressures of carbon monoxide + nitrogen solid solutions have been measured in the region of the λ-transition (55–63°K) by a condensation technique. Measurements on bulk solutions were not practicable for T < (0.9 times the temperature of the triple point) because very long equilibrium times were encountered. Equilibrium pressures for three solutions of fixed vapour concentration (7.5, 20 and 39 % nitrogen) are reported and the excess Gibbs energies have been derived as a function of temperature. Deviations from ideal behaviour are small in both the α and β solid phases. Conventional vapour pressure measurements on a bulk specimen of pure carbon monoxide (∼1 cm3) are also described and the results compared with those of other workers; the agreement is good.

Article information

Article type
Paper

Trans. Faraday Soc., 1968,64, 1461-1469

Equilibrium vapour pressures of carbon monoxide + nitrogen solid solutions

J. A. Morrison, D. M. T. Newsham and R. D. Weir, Trans. Faraday Soc., 1968, 64, 1461 DOI: 10.1039/TF9686401461

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