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The reactions between carbon monoxide, chlorine and nitrogen dioxide have been studied over the temperature range 381–473°C by manometric and photometric methods. The kinetic equations for this system has been established, and the proposed mechanism leads to a velocity constant for the reaction, COCl + NO2→CO2+NO + Cl of k= 108.84 exp (+160±250/RT)l. mole–1 sec–1.
J. H. Thomas and G. R. Woodman, Trans. Faraday Soc., 1967, 63, 2728 DOI: 10.1039/TF9676302728
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