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Volume 63, 1967
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Photolysis of methyl formate

Abstract

The vapour-phase photolysis of methyl formate has been studied in the temperature range 30–103°C. Methoxyl, methyl and formyl radicals are generated in the photolysis and their reactions have been studied. In this temperature region, radical-radical reactions have been shown to be more important than reactions involving hydrogen atom absotraction from methyl formate by the radicals, and rate constants have been measured or deduced for several such reactions.

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Article type: Paper
DOI: 10.1039/TF9676301656
Trans. Faraday Soc., 1967,63, 1656-1664

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    Photolysis of methyl formate

    M. J. Y. Quee and J. C. J. Thynne, Trans. Faraday Soc., 1967, 63, 1656
    DOI: 10.1039/TF9676301656

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