Volume 63, 1967
From the journal:

Transactions of the Faraday Society

Electron spin resonance studies of fundamental processes in radiation and photo-chemistry. Part 4.—γ-Irradiated potassium alkyl sulphates between 77 and 300°K

P. B. Ayscough  and  A. K. Roy  

Abstract

The effect of ionizing radiation on potassium methyl and ethyl sulphates has been examined, using electron spin resonance to identify the trapped paramagnetic species. After γ-irradiation at 77°K the radicals ĊH2OSO–3 and CH3ĊHOSO–3 predominate in the methyl and ethyl compounds respectively, and some SO–3 is seen. Above 200°K only SO–3 remains; its identity was confirmed by an analysis of the 33S hyperfine interaction. Mechanisms for the radiolysis are discussed.

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Article information

DOI
https://doi.org/10.1039/TF9676301106
Article type
Paper

Trans. Faraday Soc., 1967,63, 1106-1114

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Electron spin resonance studies of fundamental processes in radiation and photo-chemistry. Part 4.—γ-Irradiated potassium alkyl sulphates between 77 and 300°K

P. B. Ayscough and A. K. Roy, Trans. Faraday Soc., 1967, 63, 1106 DOI: 10.1039/TF9676301106

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