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Issue 33, 2017
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Enhanced stability of a rubrene analogue with a brickwork packing motif

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Abstract

In this study, a rubrene analogue (SF10-RUB) was designed and synthesised. Due to the introduction of pentafluorobenzene into the molecular structure, the packing motif of this material changed from a nonclassical herringbone packing to a brickwork packing. Moreover, intermolecular interactions, including C–H⋯π, S⋯F, C–H⋯F, and F⋯H interactions, were much more in SF10-RUB than those in its courterpart (SF0-RUB and RUB), together with its lower HOMO level, which made this material much more stable than other materials.

Graphical abstract: Enhanced stability of a rubrene analogue with a brickwork packing motif

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Article information


Submitted
25 Apr 2017
Accepted
31 Jul 2017
First published
01 Aug 2017

J. Mater. Chem. C, 2017,5, 8376-8379
Article type
Communication

Enhanced stability of a rubrene analogue with a brickwork packing motif

J. Li, Z. Ni, X. Zhang, R. Li, H. Dong and W. Hu, J. Mater. Chem. C, 2017, 5, 8376
DOI: 10.1039/C7TC01790A

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