Solution-processed copper oxide interlayers for broadband PbS quantum-dot photodiodes

Abstract

Metal oxide interlayers are promising for optoelectronic applications due to solution processability, optical transparency, and excellent charge blocking properties. Highly efficient, air-stable quantum dot photodetectors have been reported using solution-processed metal oxide interlayers. However, the processing temperatures are high, significantly limiting their potential for roll-to-roll processing. Here, we report low temperature-processed broadband PbS quantum dot photodiodes by employing a solution-processed CuO_x interlayer. The resulting photodiodes exhibit a low dark current of 10 nA cm⁻² with a detectivity over 10¹³ Jones. Finally, we demonstrate a flexible inorganic photodiode on a polyethylene terephthalate substrate.