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Issue 11, 2020
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Recent advances in doping engineering of black phosphorus

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Abstract

Black phosphorus (BP), as a typical layered two-dimensional (2D) material, has attracted tremendous attention due to its high carrier mobility, unique in-plane anisotropic structure and tunable direct bandgap. However, its instability due to environmental effects somehow limited its further progress in device applications. Actually, doping engineering has been proven to be an efficient and simple method to improve both the physical and chemical properties of BP, and the performance of BP in both academic and engineering applications. Herein, we review the recent progress of BP doping engineering including substitution doping, intercalation doping, surface charge transfer doping and electrostatic carrier doping. Finally, the challenges and future opportunities for the doping engineering of BP are also provided.

Graphical abstract: Recent advances in doping engineering of black phosphorus

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Article information


Submitted
10 Jan 2020
Accepted
26 Feb 2020
First published
27 Feb 2020

J. Mater. Chem. A, 2020,8, 5421-5441
Article type
Review Article

Recent advances in doping engineering of black phosphorus

H. Hu, Z. Shi, K. Khan, R. Cao, W. Liang, A. K. Tareen, Y. Zhang, W. Huang, Z. Guo, X. Luo and H. Zhang, J. Mater. Chem. A, 2020, 8, 5421
DOI: 10.1039/D0TA00416B

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