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Issue 12, 2019
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A nitrogen-containing all-solid-state hyperbranched polymer electrolyte for superior performance lithium batteries

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Abstract

Polyether-based materials, especially poly(ethylene oxide) (PEO) and derivatives thereof, have been extensively studied as Li-conducting all-solid-state polymer electrolytes (SPEs) for Li-based batteries due to their specific advantages such as easy fabrication, high safety, and outstanding compatibility with lithium salts. However, PEO-based polymers usually have too strong complexation ability with lithium ions and high crystallinity, resulting in a low lithium-ion transference number and room temperature ionic conductivity. In this study, we choose hyperbranched polyethylenimine (HPEI) as the core of a SPE matrix, while polyester segments as the arms through sequential ring-open polymerization (ROP) of glycolide (GC) and ε-caprolactone (CL). Specifically, the HPEI core containing N atoms can promote the dissociation of lithium salts, while the polyester segments can effectively dissolve lithium salts and transport ions. Furthermore, the SPE (HPEI–PGC–PCL/LiTFSI) is cast onto a ceramic film containing ceramic nanowires to prepare a composite SPE (CSPE), which can further construct ion transport channels at the interface of the polymer and nanowires. Synergizing the advantages of HPEI–PGC–PCL and ceramic nanowires, the CSPE exhibits superior electrochemical performance. Especially, the LiFePO4/CSPE/Li cell exhibits a discharge capacity of 162 mA h g−1 at the C-rates of 0.2, 0.5 and 1C, and an average discharge capacity of 158 mA h g−1 with an average coulombic efficiency of 99.8% over 200 cycles at 0.5C. More importantly, the LiCoO2/CSPE/Li cell also shows very good cycling performance (reaches 130 mA h g−1 at a current density of 0.06 mA cm−2) and rate capacity (reaches 80 mA h g−1 at a current density of 0.3 mA cm−2). This work highlights a new and novel host material that has the potential to be used as a high performance all-solid-state electrolyte for solid-state batteries.

Graphical abstract: A nitrogen-containing all-solid-state hyperbranched polymer electrolyte for superior performance lithium batteries

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Supplementary files

Article information


Submitted
06 Jan 2019
Accepted
18 Feb 2019
First published
18 Feb 2019

J. Mater. Chem. A, 2019,7, 6801-6808
Article type
Paper

A nitrogen-containing all-solid-state hyperbranched polymer electrolyte for superior performance lithium batteries

L. Zhang, S. Wang, J. Li, X. Liu, P. Chen, T. Zhao and L. Zhang, J. Mater. Chem. A, 2019, 7, 6801
DOI: 10.1039/C9TA00180H

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