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Issue 32, 2018
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Carbonization of covalent triazine-based frameworks via ionic liquid induction

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Abstract

A series of porous organic polymers (POPs) were synthesized using tetrahedral 1,3,5,7-tetracyanoadamantane as the main building block. The POP frameworks in the presence of different amounts of molten ZnCl2 as an ionic liquid were allowed to alter/enhance the Brunauer–Emmett–Teller (BET) surface areas of the POPs in the range from 760 to 1560 m2 g−1. The mechanism of the carbonization was unveiled by IR, EA and solid-state NMR; which is in situ ionic liquid induced polymerization and carbonization of the POPs.

Graphical abstract: Carbonization of covalent triazine-based frameworks via ionic liquid induction

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Publication details

The article was received on 12 Jun 2018, accepted on 25 Jul 2018 and first published on 25 Jul 2018


Article type: Communication
DOI: 10.1039/C8TA05583A
Citation: J. Mater. Chem. A, 2018,6, 15564-15568
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    Carbonization of covalent triazine-based frameworks via ionic liquid induction

    J. Jia, Z. Chen, Y. Belmabkhout, K. Adil, P. M. Bhatt, V. A. Solovyeva, O. Shekhah and M. Eddaoudi, J. Mater. Chem. A, 2018, 6, 15564
    DOI: 10.1039/C8TA05583A

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