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Issue 29, 2018
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A renewable wood-derived cathode for Li–O2 batteries

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Abstract

In this work, we developed a renewable wood-derived cathode with well-aligned elongated microchannels for high-performance Li–O2 batteries. The cathode was obtained from natural wood following carbonization, activation, and then loading of RuO2 nanoparticles (4.15 wt%) as catalysts (RuO2/WD-C). The cathode has a three-dimensional, high stability carbon matrix, uniformly anchored catalysts, and well-aligned porous microchannels. As a result, the specific areal capacity of the assembled batteries exceeds 8 mA h cm−2 and the charge terminal potential is lower than 3.8 V at 0.1 mA cm−2. The energy efficiency was improved up to 91.9% and exceeded 87.1% after 100 cycles (curtailed capacity of 0.5 mA h cm−2 at 0.2 mA cm−2). Furthermore, the RuO2/WD-C cathode can be fully regenerated from a deep discharge–charge cycle or 100 curtailed-capacity cycles by simply washing with water. The areal capacity of the regenerated RuO2/WD-C cathode is comparable to the performance of the initial cathode. The cut-off voltage was above 2.6 V following 200 cycles. Even when regenerated for the second time, the RuO2/WD-C cathode still demonstrated almost the same high performance as the initial one, indicating its high stability and excellent renewability.

Graphical abstract: A renewable wood-derived cathode for Li–O2 batteries

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Publication details

The article was received on 16 Mar 2018, accepted on 26 Jun 2018 and first published on 27 Jun 2018


Article type: Paper
DOI: 10.1039/C8TA04703K
J. Mater. Chem. A, 2018,6, 14291-14298

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    A renewable wood-derived cathode for Li–O2 batteries

    C. Zhu, L. Du, J. Luo, H. Tang, Z. Cui, H. Song and S. Liao, J. Mater. Chem. A, 2018, 6, 14291
    DOI: 10.1039/C8TA04703K

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