A long-term corrosion barrier with an insulating boron nitride monolayer

Abstract

Graphene has been demonstrated as an ultrathin and light-weight corrosion barrier because of its high impermeability. However, it fails to prevent the Cu corrosion over a long term because the high conductivity of graphene enables the formation of a galvanic cell and promotes the electrochemical reaction. Here we theoretically and experimentally study a boron nitride (BN) monolayer as a long-term corrosion barrier for Cu. Our density functional theory calculations show that the potential barrier for O₂ to pass through BN is close to that of graphene. The long-term barrier characteristics of BN and graphene are comparably evaluated by aging in an ambient environment for 160 days. Morphological and spectroscopic characterization shows that a BN monolayer has much better long-term barrier performance than graphene. X-ray photoelectron spectroscopy analysis shows that the Cu²⁺ percentage of the aging Cu sample with a BN barrier is reduced by around 15 times compared with that covered by graphene. The superior long-term barrier performance of a BN monolayer can be understood to be a result of its high impermeability and insulating characteristics, which suppress the galvanic corrosion under the ambient environment. These studies reveal that a BN monolayer is a more effective long-term corrosion barrier than graphene.