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Issue 17, 2013
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Carbon nanomaterial-assisted morphological tuning for thermodynamic and kinetic destabilization in sodium alanates

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Abstract

In the present work, we develop an effective strategy, i.e., carbon nanomaterial-assisted morphological tuning, for both thermodynamic and kinetic destabilization in complex hydrides based on the interaction between the complex anion and the carbon matrix. The NaAlH4/carbon nanomaterials of graphene nanosheets (GNs), fullerene (C60) and mesoporous carbon (MC) were selected as model systems for illustrating the positive effect of carbon nanomaterial-assisted morphological tuning. It is demonstrated that through the dissolution–recrystallization process, the morphologies of NaAlH4 can be altered from the scale-like continuous structure for the GN-assisted sample, to flower-like structures with diameters ranging from 5 to 10 μm for the C60-assisted sample and to uniform particles with an average diameter of about 2 μm for the MC-assisted sample. Correspondingly, the onset temperature for dehydrogenation of NaAlH4 is reduced to about 188, 185 and 160 °C for the samples assisted with GNs, C60 and MC, respectively, much lower than 210 °C for the pristine sample. A remarkable reduction in activation energy for three-step dehydrogenation is also obtained in NaAlH4/carbon nanomaterial composites relative to the pristine sample, and the improved efficiency of carbon nanomaterials for kinetics is found to be in the order of MC > C60 > GNs. These positive improvements can be attributed to both the particle refinement and interaction between NaAlH4 and the carbon nanomaterial that are in intimate contact with each other, which are not only evidenced by FE-SEM observation, but also supported by 27Al solid-state NMR characterization.

Graphical abstract: Carbon nanomaterial-assisted morphological tuning for thermodynamic and kinetic destabilization in sodium alanates

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Article information


Submitted
09 Jan 2013
Accepted
20 Feb 2013
First published
20 Feb 2013

J. Mater. Chem. A, 2013,1, 5238-5246
Article type
Paper

Carbon nanomaterial-assisted morphological tuning for thermodynamic and kinetic destabilization in sodium alanates

Y. Li, F. Fang, H. Fu, J. Qiu, Y. Song, Y. Li, D. Sun, Q. Zhang, L. Ouyang and M. Zhu, J. Mater. Chem. A, 2013, 1, 5238
DOI: 10.1039/C3TA00102D

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