Room-temperature AIE ionic liquid crystals based on diphenylacrylonitrile-imidazole salts

Abstract

Although various AIE liquid crystals have been studied, AIE ionic liquid crystals (ILCs) are almost unknown to date. In this work, a series of novel AIE ILCs based on diphenylacrylonitrile-imidazole salts bridged by soft spacers with different anions were prepared in yields of 63–80%. The mesomorphic, photophysical and electrochemical properties were investigated systematically to elucidate the relationship between structures and properties. The results implied that they were the first room-temperature AIE ILCs with wide ranges of mesomorphic temperature, good fluorescence emission in both the solid state and mesophase, and stable electrochemical behaviour. The samples with one alkyl chain possessed the SmA₂ mesophase while the samples with two alkyl chains prefered the Col_h mesophase. The larger anions resulted in the bigger layer spacing length for the SmA₂ mesophase and smaller values of n_cell in each slice of Col_h mesophase. The fluorescence quantum yields in the mesophase maintained reasonable values (0.15–0.22), which decreased a little in comparison with that in solid films (0.18–0.26) due to the orderly molecular stacking in the mesophase. The cyclic voltammetry experiments confirmed that all of them possessed similar and stable electrochemical behaviour. This research not only presented the first room-temperature AIE ILCs with excellent mesomorphic, photophysical and electrochemical properties, but also elucidated the relationship between structures and properties to a certain degree, contributing to the further construction of novel AIE ILCs with excellent mesomorphic, photophysical and electrochemical properties.