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Issue 32, 2019
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Can one determine the density of an individual synthetic macromolecule?

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Abstract

Dendronized polymers (DPs) are large and compact main-chain linear polymers with a cylindrical shape and cross-sectional diameters of up to ∼15 nm. They are therefore considered molecular objects, and it was of interest whether given their experimentally accessible, well-defined dimensions, the density of individual DPs could be determined. We present measurements on individual, deposited DP chains, providing molecular dimensions from scanning and transmission electron microscopy and mass-per-length values from quantitative scanning transmission electron microscopy. These results are compared with density values obtained from small-angle X-ray scattering on annealed bulk specimen and with classical envelope density measurements, obtained using hydrostatic weighing or a density gradient column. The samples investigated comprise a series of DPs with side groups of dendritic generations g = 1–8. The key findings are a very large spread of the density values over all samples and methods, and a consistent increase of densities with g over all methods. While this work highlights the advantages and limitations of the applied methods, it does not provide a conclusive answer to the question of which method(s) to use for the determination of densities of individual molecular objects. We are nevertheless confident that these first attempts to answer this challenging question will stimulate more research into this important aspect of polymer and soft matter science.

Graphical abstract: Can one determine the density of an individual synthetic macromolecule?

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Publication details

The article was received on 19 Jun 2019, accepted on 16 Jul 2019 and first published on 23 Jul 2019


Article type: Paper
DOI: 10.1039/C9SM01220F
Soft Matter, 2019,15, 6547-6556

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    Can one determine the density of an individual synthetic macromolecule?

    D. Messmer, A. Sánchez-Ferrer, S. Tacke, H. Yu, H. Nüsse, J. Klingauf, R. Wepf, M. Kröger, A. Halperin, R. Mezzenga and A. D. Schlüter, Soft Matter, 2019, 15, 6547
    DOI: 10.1039/C9SM01220F

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