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Issue 30, 2016
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Solid-supported polymer bilayers formed by coil–coil block copolymers

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Abstract

The formation and physical properties of solid-supported polymer bilayers (SPBs) on an adhesive substrate have been explored by dissipative particle dynamics simulations. A SPB is developed by the adsorption of vesicles formed by diblock copolymers in a selective solvent. The adsorbed vesicle can remain intact or become ruptured into a SPB, depending on the interaction between solvophobic blocks and solvent and the interaction between solvophilic blocks and the substrate. The morphological phase diagram of adsorbed vesicles is acquired. The influence of polymer adhesion strength and solvophobicity on the geometrical and mechanical properties of a SPB is systematically studied as well. It is found that vesicular disruption is easily triggered for strong adhesion strength. Moreover, for strong adhesion strength and weak solvophobicity, the fluctuation of membrane height is impeded while the area of fluctuation is enhanced.

Graphical abstract: Solid-supported polymer bilayers formed by coil–coil block copolymers

  • This article is part of the themed collection: Polymers
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Article information


Submitted
26 Mar 2016
Accepted
30 Jun 2016
First published
04 Jul 2016

Soft Matter, 2016,12, 6442-6450
Article type
Paper

Solid-supported polymer bilayers formed by coil–coil block copolymers

Y. Yang, H. Tsao and Y. Sheng, Soft Matter, 2016, 12, 6442
DOI: 10.1039/C6SM00741D

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