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Issue 28, 2016
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Wetting against the nap – how asperity inclination determines unidirectional spreading

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Abstract

We have carried out wetting experiments on textured surfaces with high aspect ratio asperities in the Wenzel state. When inclination is imparted to the asperities, we observe a strictly unidirectional spreading opposite to the direction in which the asperities point. The advancing contact angle decreases markedly as inclination increases. A crude numerical analysis successfully accounts for this behaviour, highlighting the interplay between Gibbs pinning at the top of the structures and imbibition along the valleys between them. In Gibbs pinning non-linearities play a major role and we find that simple line averaging – i.e. a rule of mixture – cannot account for this evolution except for weak surface perturbations, i.e. large inclinations.

Graphical abstract: Wetting against the nap – how asperity inclination determines unidirectional spreading

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Supplementary files

Article information


Submitted
29 Feb 2016
Accepted
20 Jun 2016
First published
22 Jun 2016

Soft Matter, 2016,12, 6067-6072
Article type
Paper

Wetting against the nap – how asperity inclination determines unidirectional spreading

E. Contraires, J. Teisseire, E. Søndergård and E. Barthel, Soft Matter, 2016, 12, 6067
DOI: 10.1039/C6SM00523C

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