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Issue 5, 2012
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Adsorption/desorption-induced phase transformation in the self-assembled monolayers of an amphiphilic rod–coil block copolymer

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Abstract

In the polymeric self-assembled monolayer of an amphiphilic rod–coil copolymer consisting of a planar-adsorbed rod-like block and an anchoring coil block, phase transformation from an isotropic to nematic monolayer and then to a crystalline monolayer occurs during adsorption of chains to the surface in solution, whereas the monolayer reorganizes to anisotropic surface micelles when immersed in a coil-selective solvent.

Graphical abstract: Adsorption/desorption-induced phase transformation in the self-assembled monolayers of an amphiphilic rod–coil block copolymer

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Supplementary files

Article information


Submitted
18 Oct 2011
Accepted
01 Dec 2011
First published
19 Dec 2011

Soft Matter, 2012,8, 1309-1312
Article type
Communication

Adsorption/desorption-induced phase transformation in the self-assembled monolayers of an amphiphilic rod–coil block copolymer

S. Jeong, M. Song and J. Park, Soft Matter, 2012, 8, 1309
DOI: 10.1039/C2SM06983K

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