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Issue 6, 2018
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Light-driven hydrogen evolution catalyzed by a cobaloxime catalyst incorporated in a MIL-101(Cr) metal–organic framework

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Abstract

A cobaloxime H2 evolution catalyst with a hydroxo-functionalized pyridine ligand, Co(dmgH)2(4-HEP)Cl [dmgH = dimethylglyoxime, 4-HEP = 4-(2-hydroxyethyl)pyridine] was immobilized on a chromium terephthalate metal–organic framework (MOF), MIL-101(Cr), to construct a MOF-catalyst hybrid which displays good photocatalytic H2 evolution activity. The longevity of the cobaloxime catalyst is increased by MOF incorporation, but limited by the stability of the cobalt–pyridine bond under turnover conditions.

Graphical abstract: Light-driven hydrogen evolution catalyzed by a cobaloxime catalyst incorporated in a MIL-101(Cr) metal–organic framework

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Publication details

The article was received on 15 Feb 2018, accepted on 09 Apr 2018 and first published on 01 May 2018


Article type: Communication
DOI: 10.1039/C8SE00072G
Sustainable Energy Fuels, 2018,2, 1148-1152
  • Open access: Creative Commons BY-NC license
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    Light-driven hydrogen evolution catalyzed by a cobaloxime catalyst incorporated in a MIL-101(Cr) metal–organic framework

    S. Roy, A. Bhunia, N. Schuth, M. Haumann and S. Ott, Sustainable Energy Fuels, 2018, 2, 1148
    DOI: 10.1039/C8SE00072G

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