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Issue 39, 2020

Palladium-catalyzed hydroalkylation of methylenecyclopropanes with simple hydrazones

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Abstract

A palladium-catalyzed hydroalkylation reaction of methylenecyclopropanes via highly selective C–C σ-bond scission was achieved under mild conditions, in which simple hydrazones served as carbanion equivalents. This method featured good functional group compatibility, affording high yields of C-alkylated terminal alkenes.

Graphical abstract: Palladium-catalyzed hydroalkylation of methylenecyclopropanes with simple hydrazones

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Article information


Submitted
28 Feb 2020
Accepted
14 May 2020
First published
15 May 2020

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2020,11, 10759-10763
Article type
Edge Article

Palladium-catalyzed hydroalkylation of methylenecyclopropanes with simple hydrazones

J. Yao, Z. Chen, L. Yu, L. Lv, D. Cao and C. Li, Chem. Sci., 2020, 11, 10759 DOI: 10.1039/D0SC01221A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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