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Issue 28, 2019
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Interplay between spin-crossover and luminescence in a multifunctional single crystal iron(ii) complex: towards a new generation of molecular sensors

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Abstract

We present a new example of a mononuclear iron(II) complex exhibiting a correlated spin-crossover (SCO) transition and strong fluorescence, whose coordination sphere is saturated, for the first time, by six phosphorescent ligands. The interplay between SCO and light emission properties in the thermal region of the spin transition was investigated by means of magnetic, fluorescence, optical absorption and optical microscopy measurements on a single crystal. Overall, the results show an excellent correlation between fluorescence and magnetic data of the present gradual transition, indicating an extreme sensitivity of the optical activity of the ligand to the spin state of the active iron(II) ions. These results open the way for conceiving new prototypes of pressure and temperature sensors based on this synergy between SCO and luminescence properties. In particular, the fact that cooperative SCO material is not a prerequisite for obtaining such synergetic effects, is useful for the design of thin films or nanoparticles, in which the cooperativity is reduced, for appropriate implementation in nanosized devices to enhance the sensing properties at the nanoscale.

Graphical abstract: Interplay between spin-crossover and luminescence in a multifunctional single crystal iron(ii) complex: towards a new generation of molecular sensors

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Publication details

The article was received on 13 May 2019, accepted on 06 Jun 2019 and first published on 14 Jun 2019


Article type: Edge Article
DOI: 10.1039/C9SC02331C
Chem. Sci., 2019,10, 6791-6798
  • Open access: Creative Commons BY-NC license
    All publication charges for this article have been paid for by the Royal Society of Chemistry

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    Interplay between spin-crossover and luminescence in a multifunctional single crystal iron(II) complex: towards a new generation of molecular sensors

    B. Benaicha, K. Van Do, A. Yangui, N. Pittala, A. Lusson, M. Sy, G. Bouchez, H. Fourati, C. J. Gómez-García, S. Triki and K. Boukheddaden, Chem. Sci., 2019, 10, 6791
    DOI: 10.1039/C9SC02331C

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