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Issue 25, 2019
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A ruthenium(ii)-catalyzed C–H allenylation-based approach to allenoic acids

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Abstract

A Ru(II)-catalyzed direct access to various functionalized allenoic acids via C–H allenylation of readily available aryl carboxylic acids with propargylic acetates is reported. Axially chiral allenoic acids could be obtained in high ee by using optically active propargylic acetates through a chirality transfer strategy.

Graphical abstract: A ruthenium(ii)-catalyzed C–H allenylation-based approach to allenoic acids

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Supplementary files

Article information


Submitted
02 Feb 2019
Accepted
04 May 2019
First published
10 May 2019

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2019,10, 6316-6321
Article type
Edge Article

A ruthenium(II)-catalyzed C–H allenylation-based approach to allenoic acids

X. Wu, J. Fan, C. Fu and S. Ma, Chem. Sci., 2019, 10, 6316
DOI: 10.1039/C9SC00603F

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