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Issue 11, 2019
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Reductive annulations of arylidene malonates with unsaturated electrophiles using photoredox/Lewis acid cooperative catalysis

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Abstract

A cooperative Lewis acid/photocatalytic reduction of salicylaldehyde-derived arylidene malonates provides access to a versatile, stabilized radical anion enolate. Using these unusual umpolung operators, we have developed a novel route to access densely functionalized carbo- and heterocycles through a radical annulation addition pathway.

Graphical abstract: Reductive annulations of arylidene malonates with unsaturated electrophiles using photoredox/Lewis acid cooperative catalysis

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Publication details

The article was received on 18 Jan 2019, accepted on 03 Feb 2019 and first published on 06 Feb 2019


Article type: Edge Article
DOI: 10.1039/C9SC00302A
Chem. Sci., 2019,10, 3353-3359
  • Open access: Creative Commons BY-NC license
    All publication charges for this article have been paid for by the Royal Society of Chemistry

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    Reductive annulations of arylidene malonates with unsaturated electrophiles using photoredox/Lewis acid cooperative catalysis

    R. C. Betori, B. R. McDonald and K. A. Scheidt, Chem. Sci., 2019, 10, 3353
    DOI: 10.1039/C9SC00302A

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