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Issue 13, 2019
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Alkene hydrosilylation catalyzed by easily assembled Ni(II)-carboxylate MOFs

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Abstract

We report the first Ni MOF catalysts for anti-Markovnikov hydrosilylation of alkenes. These catalysts are bench-stable and easily-assembled from simple Ni salts and carboxylic acids. The best catalyst gives turnover numbers up to 9500 and is robust even after 10 recycling runs. The catalyst can be applied for the hydrosilylation of a wide range of alkenes, achieving good synthetic utility and functional group tolerance.

Graphical abstract: Alkene hydrosilylation catalyzed by easily assembled Ni(ii)-carboxylate MOFs

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Publication details

The article was received on 09 Jan 2019, accepted on 22 Feb 2019 and first published on 25 Feb 2019


Article type: Edge Article
DOI: 10.1039/C9SC00126C
Chem. Sci., 2019,10, 3791-3795
  • Open access: Creative Commons BY license
    All publication charges for this article have been paid for by the Royal Society of Chemistry

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    Alkene hydrosilylation catalyzed by easily assembled Ni(II)-carboxylate MOFs

    Z. Zhang, L. Bai and X. Hu, Chem. Sci., 2019, 10, 3791
    DOI: 10.1039/C9SC00126C

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