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Issue 13, 2019
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Alkene hydrosilylation catalyzed by easily assembled Ni(ii)-carboxylate MOFs

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Abstract

We report the first Ni MOF catalysts for anti-Markovnikov hydrosilylation of alkenes. These catalysts are bench-stable and easily-assembled from simple Ni salts and carboxylic acids. The best catalyst gives turnover numbers up to 9500 and is robust even after 10 recycling runs. The catalyst can be applied for the hydrosilylation of a wide range of alkenes, achieving good synthetic utility and functional group tolerance.

Graphical abstract: Alkene hydrosilylation catalyzed by easily assembled Ni(ii)-carboxylate MOFs

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Article information


Submitted
09 Jan 2019
Accepted
22 Feb 2019
First published
25 Feb 2019

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2019,10, 3791-3795
Article type
Edge Article

Alkene hydrosilylation catalyzed by easily assembled Ni(II)-carboxylate MOFs

Z. Zhang, L. Bai and X. Hu, Chem. Sci., 2019, 10, 3791
DOI: 10.1039/C9SC00126C

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