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Issue 9, 2019
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Electrochemical oxidative C–H/S–H cross-coupling between enamines and thiophenols with H2 evolution

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Abstract

Electrochemical oxidative C–H/S–H cross-coupling has been developed to construct the C–S bond in a highly straightforward and efficient manner. Various enamines and (hetero)aryl thiols could be transformed smoothly under undivided electrolytic cell conditions. Moreover, this electrosynthesis strategy not only avoided the use of chemical oxidants and transition metal catalysts, but also exhibited excellent atom economy.

Graphical abstract: Electrochemical oxidative C–H/S–H cross-coupling between enamines and thiophenols with H2 evolution

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Supplementary files

Article information


Submitted
17 Nov 2018
Accepted
05 Jan 2019
First published
18 Jan 2019

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2019,10, 2791-2795
Article type
Edge Article

Electrochemical oxidative C–H/S–H cross-coupling between enamines and thiophenols with H2 evolution

D. Li, S. Li, C. Peng, L. Lu, S. Wang, P. Wang, Y. Chen, H. Cong and A. Lei, Chem. Sci., 2019, 10, 2791
DOI: 10.1039/C8SC05143G

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