Issue 11, 2019
From the journal:

Chemical Science

Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators†

Rubén Sáez,a   Ciaran McArdle,‡b   Fouad Salhi,c   Jordi Marquet ORCID logo *a  and  Rosa M. Sebastián ORCID logo §*a  

* Corresponding authors

a Chemistry Department, Centro de Innovación en Química Avanzada (ORFEO-CINQA), Universitat Autònoma de Barcelona, 08193 Cerdanyola del Vallès, Barcelona, Spain
E-mail: rosamaria.sebastian@uab.es

b Henkel Ireland Operations and Research Ltd., Tallaght Business Park, Whitestown Road, Tallaght, Dublin 24, Ireland

c Henkel Corporation, Edifici Eureka, Universitat Autònoma de Barcelona, 08193 Cerdanyola del Vallès, Barcelona, Spain

Abstract

A hydrogenated frustrated Lewis pair ([TMPH+][HB(C6F5)3−]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block sequences for the first time in the long history of these materials.

Graphical abstract: Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators

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Article information

DOI
https://doi.org/10.1039/C8SC04729D
Article type
Edge Article
Submitted
23 Oct 2018
Accepted
30 Jan 2019
First published
01 Feb 2019
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2019,10, 3295-3299

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Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators

R. Sáez, C. McArdle, F. Salhi, J. Marquet and R. M. Sebastián, Chem. Sci., 2019, 10, 3295 DOI: 10.1039/C8SC04729D

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