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Issue 39, 2018
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Four-coordinate triarylborane synthesis via cascade B–Cl/C–B cross-metathesis and C–H bond borylation

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Abstract

To develop a simple and efficient synthetic method for four-coordinate triarylboranes, we herein describe a tandem highly selective B–Cl/C–B cross-metathesis of two of the same or different arylboranes and C–H bond borylation to synthesize four-coordinate triarylboranes with a broad substrate scope. By switching substituent groups of the target molecules, different emission wavelengths can be achieved from 467 nm to 583 nm with aggregation-induced emission (AIE) properties.

Graphical abstract: Four-coordinate triarylborane synthesis via cascade B–Cl/C–B cross-metathesis and C–H bond borylation

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Publication details

The article was received on 23 May 2018, accepted on 10 Aug 2018 and first published on 13 Aug 2018


Article type: Edge Article
DOI: 10.1039/C8SC02281J
Citation: Chem. Sci., 2018,9, 7666-7672
  • Open access: Creative Commons BY license
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    Four-coordinate triarylborane synthesis via cascade B–Cl/C–B cross-metathesis and C–H bond borylation

    K. Yang, G. Zhang and Q. Song, Chem. Sci., 2018, 9, 7666
    DOI: 10.1039/C8SC02281J

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