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Issue 5, 2017
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Catalyst displacement assay: a supramolecular approach for the design of smart latent catalysts for pollutant monitoring and removal

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Abstract

Latent catalysts can be tuned to function smartly by assigning a sensing threshold using the displacement approach for targeted analytes. Three cyano-bridged bimetallic complexes were synthesized as “smart” latent catalysts through the supramolecular assembly of different metallic donors [FeII(CN)6]4−, [FeII(tBubpy)(CN)4]2−, and FeII(tBubpy)2(CN)2 with a metallic acceptor [CuII(dien)]2+. The investigation of both their thermodynamic and kinetic properties on binding with toxic pollutants provided insight into their smart off–on catalytic capabilities, enabling us to establish a threshold-controlled catalytic system for the degradation of pollutants such as cyanide and oxalate. With these smart latent catalysts, a new catalyst displacement assay (CDA) was demonstrated and applied in a real wastewater treatment process to degrade cyanide pollutants in both domestic (level I, untreated) and industrial wastewater samples collected in Hong Kong, China. The smart system was adjusted to be able to initiate the catalytic oxidation of cyanide at a threshold concentration of 20 μM (the World Health Organization’s suggested maximum allowable level for cyanide in wastewater) to the less harmful cyanate under ambient conditions.

Graphical abstract: Catalyst displacement assay: a supramolecular approach for the design of smart latent catalysts for pollutant monitoring and removal

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Supplementary files

Article information


Submitted
21 Dec 2016
Accepted
01 Mar 2017
First published
02 Mar 2017

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2017,8, 3812-3820
Article type
Edge Article

Catalyst displacement assay: a supramolecular approach for the design of smart latent catalysts for pollutant monitoring and removal

C. Chow, P. Ho, W. Wong, Y. Lu, Q. Tang and C. Gong, Chem. Sci., 2017, 8, 3812
DOI: 10.1039/C6SC05584B

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