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Issue 1, 2017
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Layered host–guest long-afterglow ultrathin nanosheets: high-efficiency phosphorescence energy transfer at 2D confined interface

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Abstract

Tuning and optimizing the efficiency of light energy transfer play an important role in meeting modern challenges of minimizing energy loss and developing high-performance optoelectronic materials. However, attempts to fabricate systems giving highly efficient energy transfer between luminescent donor and acceptor have achieved limited success to date. Herein, we present a strategy towards phosphorescence energy transfer at a 2D orderly crystalline interface. We first show that new ultrathin nanosheet materials giving long-afterglow luminescence can be obtained by assembling aromatic guests into a layered double hydroxide host. Furthermore, we demonstrate that co-assembly of these long-lived energy donors with an energy acceptor in the same host generates an ordered arrangement of phosphorescent donor–acceptor pairs spatially confined within the 2D nanogallery, which affords energy transfer efficiency as high as 99.7%. Therefore, this work offers an alternative route to develop new types of long-afterglow nanohybrids and efficient light transfer systems with potential energy, illumination and sensor applications.

Graphical abstract: Layered host–guest long-afterglow ultrathin nanosheets: high-efficiency phosphorescence energy transfer at 2D confined interface

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Supplementary files

Article information


Submitted
06 Aug 2016
Accepted
02 Sep 2016
First published
06 Sep 2016

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2017,8, 590-599
Article type
Edge Article

Layered host–guest long-afterglow ultrathin nanosheets: high-efficiency phosphorescence energy transfer at 2D confined interface

R. Gao and D. Yan, Chem. Sci., 2017, 8, 590
DOI: 10.1039/C6SC03515A

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