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Issue 7, 2015
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Organocatalytic asymmetric chlorinative dearomatization of naphthols

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Abstract

An organocatalytic asymmetric chlorinative dearomatization of naphthols was realized for the first time, providing chiral naphthalenones with a Cl-containing all-substituted stereocenter in excellent yields and enantioselectivity (up to 97% yield and 96% ee). The reaction features mild reaction conditions, good tolerance of diverse functional groups and simple reaction operation.

Graphical abstract: Organocatalytic asymmetric chlorinative dearomatization of naphthols

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Supplementary files

Article information


Submitted
09 Feb 2015
Accepted
25 Apr 2015
First published
27 Apr 2015

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2015,6, 4179-4183
Article type
Edge Article

Organocatalytic asymmetric chlorinative dearomatization of naphthols

Q. Yin, S. Wang, X. Liang, D. Gao, J. Zheng and S. You, Chem. Sci., 2015, 6, 4179
DOI: 10.1039/C5SC00494B

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