Issue 10, 2014
From the journal:

Chemical Science

Coordination copolymerization of three carboxylate linkers into a pillared layer framework†

Ananya Dutta,a   Antek G. Wong-Foya  and  Adam J. Matzger*ab  

* Corresponding authors

a Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1055, USA
E-mail: matzger@umich.edu

b Department of Macromolecular Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109-1055, USA

Abstract

Incorporation of three distinct linkers with identical functionality in a coordination copolymer is accomplished in materials designated UMCM-10, -11, and -12. Uniaxial lattice expansion, achieved in these highly porous and non-interpenetrated materials, is utilized in size-selective guest incorporation.

Graphical abstract: Coordination copolymerization of three carboxylate linkers into a pillared layer framework

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Article information

DOI
https://doi.org/10.1039/C3SC53549E
Article type
Edge Article
Submitted
27 Dec 2013
Accepted
16 Jun 2014
First published
07 Jul 2014

Chem. Sci., 2014,5, 3729-3734

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Coordination copolymerization of three carboxylate linkers into a pillared layer framework

A. Dutta, A. G. Wong-Foy and A. J. Matzger, Chem. Sci., 2014, 5, 3729 DOI: 10.1039/C3SC53549E

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