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Issue 5, 2014
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Strongest π–metal orbital coupling in a porphyrin/gold cluster system

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Abstract

Face-on and close configuration of a π-conjugated molecule on an Au cluster generates a strong π–metal coupling between the π and metal orbitals. We successfully synthesized porphyrin-coordinated Au clusters in face-on configuration at the closest distance. The interaction between the Au cluster and porphyrin was investigated by UV-vis-NIR and transient absorption measurement.

Graphical abstract: Strongest π–metal orbital coupling in a porphyrin/gold cluster system

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Supplementary files

Article information


Submitted
17 Dec 2013
Accepted
07 Feb 2014
First published
07 Feb 2014

Chem. Sci., 2014,5, 2007-2010
Article type
Edge Article
Author version available

Strongest π–metal orbital coupling in a porphyrin/gold cluster system

D. Tanaka, Y. Inuta, M. Sakamoto, A. Furube, M. Haruta, Y. So, K. Kimoto, I. Hamada and T. Teranishi, Chem. Sci., 2014, 5, 2007
DOI: 10.1039/C3SC53460J

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